Chlorate comps should not need any catalyst, and adding one is almost always a bad idea, except for when you want the composition to ignite from friction, shock etc. Chlorate and sugar mixtures are too sensitive for most people's tastes as they are, and adding an ignition sensitiser will aggravate this.
This topic should provide some further explanation.
It's probably better to avoid using chlorate comps except where you really need to (for colours and possibly burst charges), and potassium nitrate will make very impressive rockets, and much more safely. It's also cheaper and easier to get. Iron oxide can be safely used as a catalyst in nitrate based "candy propellants," if required. See
www.nakka-rocketry.net for a lot of information on this.