I'm bumping this topic to show you all a fairly interesting video posted by a russian forum member.
Again, this demonstrates how in the right environment, copper produces intense blue at very high temperatures:
http://www.youtube.c...h?v=Rds_KhCR19Q
An impressive blue!
I have synthesised oxidising oxo-acid salts of Cu, specifically copper nitrate and perchlorate, but I have found that they are so hygroscopic that they form a pool of liquid within an hour of being removed from the dessiccator. This hygroscopicity detracts from their oxidising action and also makes compositions unstable. This is a little disappointing, since perchlorate salts of Cu, such as Cu perchlorate, contain their own source of chlorine, which means that a separate chlorine-donor probably would not be required.
Also, Cu has a catalytic action, much like other transition metals. This catalytic effect might sensitise a composition, rendering it dangerously unstable to heat, percussion or friction.
From my point of view, you can't beat the 'tried and tested' non-hygroscopic Cu compounds in the +2 oxidation state- copper carbonate, copper oxide and finely powdered Cu mental (Cu in its elemental form, which has an oxidation state of zero).
I have synthesised carboxylic acid salts of Cu (oxalate, salicylate and sorbate) with promising results. I'll make a video of my experimental research and post it here- stay tuned!