realistically, whats the chances it going wrong........
Read, read, and read more. If you search the forums there are lots of posts about flash, and many safety issues are covered.
For example, small amounts of static electricity can easily ignite flash, and 5g of flash can do serious injury, even without being contained.
search the forums for links to flash injury pictures, they aren't pretty.
Don't want to put you off pyro, its a great hobby, just using flash!